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The structural change ( Figure 7E ) could potentially hinder the transamination reaction, because the loop movement might bring the -amino group of PMP into closer proximity to other amino-acid side groups, such as His192, promoting the hydrogen bond formation that may influence the reactivity of PMP with GSA

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doi:10.1097/JTO.0b013e3181d95dd4 33

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PMID: 83 BaptissartMVegaAMartinotEPommierAJHoutenSMMarceauGet al