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(42), m/z 145 is formed from BDMC keto form through a hydrogen transfer from benzene ring to C-4 and loss of a neutral moiety, in contrast m/z 119 is produced from BDMC enol form

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In addition to extracellular catabolism, intracellular GSH degradation is mediated by the ChaC GSH specific gamma-glutamylcyclotransferase family (CHAC1 and CHAC2), which cleaves GSH into 5-oxoproline and Cys-Gly 28,29

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