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It indicates either bacterial contamination or that the peptide has aggregated and fallen out of solution

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Three-dimensional reconstructions of mouse circumvallate taste buds using serial blockface scanning electron microscopy: I

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The 'LR3' designation refers to a 13-amino-acid N-terminal extension and a glutamic acid substitution at position 3, which together reduce binding affinity for IGF-binding proteins (IGFBPs) by approximately 100-fold